The gain in usable energy

Lead-acid batteries are usually planned at about half their rating because deeper cycling shortens their life. LiFePO4 batteries tolerate deeper cycling: Victron, for example, rates its LFP Smart range at about 2,500 cycles to 80% depth of discharge. So the same Ah rating delivers more usable energy.

Fridge, lights and phones with no charging
BatteryUsable energyAutonomy
100 Ah AGM at 50%600 Wh0.9 to 1.1 days
100 Ah LiFePO4 at 80%960 Wh1.5 to 1.8 days
Worked exampleCompare it with your own loads
Usable energy
960 Wh
Daily use
530 Wh
Daily charging
0 Wh
Autonomy
1.5 to 1.8 days

Switch chemistry in the calculator to see the AGM figure for the same loads.

Open in the calculator

Every charging source has to agree

A lithium battery charges best with the charging voltage and profile its maker specifies. Many campers have three or four chargers: a mains charger, a solar controller, a charge path from the alternator and sometimes a generator. Each needs a lithium setting that matches the battery datasheet, or it has to be replaced.

Questions per component before you buy
ComponentQuestion
Mains chargerDoes it have a lithium profile, and can its voltages match the battery datasheet?
Solar controllerCan it be set to LiFePO4 values, or only to lead-acid presets?
Alternator pathIs there a DC-DC charger, or does the starter battery charge the leisure battery directly?
Battery monitorCan it be reset for the new capacity and chemistry?
Fuse and isolator near the batteryAre they rated for the new battery? Ask an installer to confirm.
Control panel or habitation unitDoes the manufacturer support lithium on this unit?

The alternator is the usual surprise

Many newer vehicles with Euro 5 and 6 engines have smart alternators that vary their output voltage. Victron notes that these often give too low a charging voltage for a second battery, and long cable runs lose more along the way. A DC-DC charger regulates the charge to the leisure battery and is a common answer, but whether you need one depends on the vehicle and the wiring.

Cold limits charging, not just range

LiFePO4 batteries can usually discharge in the cold but must not be charged below a minimum temperature. That minimum differs by model. Victron lists 5 °C for some Smart batteries and 0 °C for others. If you travel in winter, check whether your battery has internal heating or low-temperature charge protection in its BMS.